2-[(3-Bromophenyl)iminomethyl]phenol
نویسندگان
چکیده
The title compound, C(13)H(10)BrNO, was prepared by reaction of 3-bromo-aniline with 2-hydroxy-benzaldehyde at 377 K. The mol-ecular structure and packing are stabilized by an intra-molecular O-H⋯N hydrogen-bond inter-action.
منابع مشابه
2-[(4-Bromophenyl)iminomethyl]-3,5-dimethoxyphenol
There are two independent mol-ecules in the asymmetric unit of the title compound, C(15)H(14)BrNO(3), with very similar geometrical parameters. Each mol-ecule adopts the phenol-imine tautomeric form, with strong intra-molecular O-H⋯N hydrogen bonds. The two mol-ecules are non-planar, the dihedral angles between the two aromatic rings being are 24.6 (2) and 30.30 (13)°.
متن کامل2-[(2-Bromophenyl)iminomethyl]-6-methylphenol
In the title compound, C(14)H(12)BrNO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The dihedral angle between the two aromatic rings is 34.26 (9)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring.
متن کاملCrystal structure of 2-{(R)-[1-(4-bromophenyl)ethyl]iminomethyl}-4-(phenyldiazenyl)phenol, a chiral photochromic Schiff base
The title chiral photochromic Schiff base compound, C21H18BrN3O, was synthesized from (R)-(+)-1-(4-bromo-phen-yl)ethyl-amine and the salicyl-aldehyde of an azo-benzene derivative. The mol-ecule corresponds to the phenol-imine tautomer, the C=N and N-C bond distances being 1.285 (3) and 1.470 (3) Å, respectively. The diazenyl group adopts a trans form, with an N=N distance of 1.256 (3) Å. The hy...
متن کامل(E)-1-[(3-Bromophenyl)iminomethyl]naphthalen-2-ol
The title compound, C(17)H(12)BrNO, exists in an enol-imine form and the mol-ecular structure features an intra-molecular O-H⋯N hydrogen bond. The dihedral angle between the benzene ring and the naphthalene ring system is 17.27 (15)°.
متن کامل{2,6-Bis[(4-bromophenyl)iminomethyl]pyridine-κ3 N,N′,N′′}trichloridochromium(III)
In the title compound, [CrCl(3)(C(19)H(13)Br(2)N(3))], the Cr(3+ )ion is coordinated by the tridentate 2,6-bis-[(4-bromo-phen-yl)imino-meth-yl]pyridine Schiff base ligand in a fac-octa-hedral geometry. The dihedral angles between the pyridine and benzene rings are 23.9 (6) and 70.7 (1)°.
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